Is basicity the sole criterion for attaining high carbon dioxide capture in deep-eutectic solvents?
Document identifier: oai:DiVA.org:ltu-77988
Access full text here:
10.1039/c9cp06017kKeyword: Engineering and Technology,
Materials Engineering,
Other Materials Engineering,
Teknik och teknologier,
Materialteknik,
Annan materialteknik,
Engineering MaterialsPublication year: 2020Relevant Sustainable Development Goals (SDGs):
The SDG label(s) above have been assigned by OSDG.aiAbstract: A critical analysis of the role of Hammett basicity (H−) and aqueous basicity (pKa) in CO2 uptake in deep-eutectic solvents (DESs) suggests that neither H− nor pKa correlates with the CO2 w/w% capacity in the studied DESs. Instead, strong “synergistic interactions” between donor and acceptor moieties satisfactorily relate to the w/w% of CO2 in DESs.
Authors
Shashi Kant Shukla
Technical Chemistry, Department of Chemistry, Chemical-Biological Centre, Umeå University, Umeå, Sweden
Other publications
>>
Dariush Nikjoo
Luleå tekniska universitet; Materialvetenskap
Other publications
>>
Jyri-Pekka Mikkola
Technical Chemistry, Department of Chemistry, Chemical-Biological Centre, Umeå University, Umeå, Sweden. Industrial Chemistry & Reaction Engineering, Department of Chemical, Engineering, Johan Gadolin Process Chemistry Centre, Åbo Akademi University, Åbo-
Other publications
>>
Record metadata
Click to view metadata
header:
identifier: oai:DiVA.org:ltu-77988
datestamp: 2021-04-19T12:42:23Z
setSpec: SwePub-ltu
metadata:
mods:
@attributes:
version: 3.7
recordInfo:
recordContentSource: ltu
recordCreationDate: 2020-03-06
identifier:
http://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-77988
10.1039/c9cp06017k
31848547
2-s2.0-85078456927
titleInfo:
@attributes:
lang: eng
title: Is basicity the sole criterion for attaining high carbon dioxide capture in deep-eutectic solvents?
abstract: A critical analysis of the role of Hammett basicity (H−) and aqueous basicity (pKa) in CO2 uptake in deep-eutectic solvents (DESs) suggests that neither H− nor pKa correlates with the CO2 w/w% capacity in the studied DESs. Instead strong “synergistic interactions” between donor and acceptor moieties satisfactorily relate to the w/w% of CO2 in DESs.
subject:
@attributes:
lang: eng
authority: uka.se
topic:
Engineering and Technology
Materials Engineering
Other Materials Engineering
@attributes:
lang: swe
authority: uka.se
topic:
Teknik och teknologier
Materialteknik
Annan materialteknik
@attributes:
lang: eng
authority: ltu
topic: Engineering Materials
genre: Research subject
@attributes:
lang: swe
authority: ltu
topic: Materialteknik
genre: Research subject
language:
languageTerm: eng
genre:
publication/journal-article
ref
note:
Published
3
Validerad;2020;Nivå 2;2020-03-06 (johcin)
name:
@attributes:
type: personal
namePart:
Shukla
Shashi Kant
role:
roleTerm: aut
affiliation: Technical Chemistry Department of Chemistry Chemical-Biological Centre Umeå University Umeå Sweden
@attributes:
type: personal
authority: ltu
namePart:
Nikjoo
Dariush
1977-
role:
roleTerm: aut
affiliation:
Luleå tekniska universitet
Materialvetenskap
nameIdentifier:
darnik
0000-0002-4628-3857
@attributes:
type: personal
namePart:
Mikkola
Jyri-Pekka
role:
roleTerm: aut
affiliation: Technical Chemistry Department of Chemistry Chemical-Biological Centre Umeå University Umeå Sweden. Industrial Chemistry & Reaction Engineering Department of Chemical Engineering Johan Gadolin Process Chemistry Centre Åbo Akademi University Åbo-Turku Finland
originInfo:
dateIssued: 2020
publisher: American Chemical Society (ACS)
relatedItem:
@attributes:
type: host
titleInfo:
title: Physical Chemistry Chemical Physics - PCCP
identifier:
1463-9076
1463-9084
part:
detail:
@attributes:
type: volume
number: 22
@attributes:
type: issue
number: 3
extent:
start: 966
end: 970
physicalDescription:
form: print
typeOfResource: text